Skip to main content

Table 2 Individual anthocyanin profile and content of blueberry pomace of different drying methods A,B,C

From: Effects of four drying methods on the quality, antioxidant activity and anthocyanin components of blueberry pomace

HPLC peak

Retention time(min)

[M + H(m/z)]

[MS/MS(m/z)]

[Δa.m.u.(m/z)]

Anthocyanin

compound

Anthocyanin content (μg/g DW)

Control

HAD

(40 °C)

HAD

(50 °C)

HAD

(60 °C)

HAD

(70 °C)

FD

MVD

MFD

1

20.905

465.1

303

162

Delphinidin-3-

O-galactoside

212.46 ± 3.93a

ND

ND

ND

ND

ND

28.89 ± 0.40c

52.85 ± 1.10b

2

22.254

465.1

303

162

Delphinidin-3-

O-glucoside

16.48 ± 1.06a

ND

ND

ND

ND

ND

6.88 ± 0.31b

ND

3

23.761

449.2

287

162

Cyanidin-3-

O-galactoside

175.11 ± 1.11a

ND

ND

ND

ND

19.43 ± 0.19d

111.35 ± 0.55c

128.80 ± 0.13b

4

24.073

435.1

303

132

Delphinidin-3-

O-arabinoside

155.43 ± 487a

3.91 ± 0.06e

2.00 ± 0.06f

2.01 ± 0.06f

ND

4.32 ± 0.01d

29.68 ± 0.07c

41.48 ± 0.05b

5

25.174

449.2

287

162

Cyanidin-3-

O-glucoside

ND

ND

ND

ND

ND

14.40 ± 0.11b

62.86 ± 0.06a

ND

6

25.437

479.1

317

162

Petunidin-3-

O-galactoside

269.23 ± 7.12a

ND

ND

ND

ND

7.94 ± 0.35d

51.99 ± 0.83c

127.18 ± 1.00b

7

26.752

479.1

317

162

Petunidin-3-

O-glucoside

178.29 ± 1.52a

28.77 ± 0.36e

17.72 ± 0.32f

17.35 ± 0.02 g

7.39 ± 0.04 h

76.05 ± 0.14d

165.12 ± 0.61b

127.38 ± 0.42c

8

27.996

463.2

301

162

Peonidin-3-

O-galactoside

107.31 ± 9.86c

ND

ND

ND

ND

32.70 ± 0.55d

112.85 ± 1.86b

124.48 ± 3.81a

9

28.229

449.2

317

132

Petunidin-3-

O-arabinoside

158.22 ± 3.31a

1.69 ± 0.02e

ND

ND

ND

22.24 ± 0.32d

71.71 ± 1.49c

82.26 ± 1.36b

10

29.071

493.1

331

162

Malvidin-3-

O-galactoside

901.31 ± 22.27a

158.95 ± 1.49d

96.91 ± 0.87e

86.40 ± 0.91f

35.35 ± 0.05 g

343.48 ± 1.47c

630.73 ± 1.11b

629.75 ± 0.28b

11

30.099

463.1

301

162

Peonidin-3-

O-glucoside

80.35 ± 2.85b

23.71 ± 0.02e

17.76 ± 0.27f

7.15 ± 0.11 g

4.47 ± 0.19 h

48.30 ± 0.48d

132.55 ± 0.87a

73.65 ± 0.59c

12

30.442

463.2

331

132

Malvidin-3-

O-arabinoside

69.40 ± 4.93a

27.62 ± 0.68e

21.06 ± 0.34f

19.83 ± 0.23 g

12.50 ± 0.24 h

41.48 ± 0.33d

59.48 ± 0.76b

53.45 ± 0.60c

13

31.334

493.1

331

162

Malvidin-3-

O-glucoside

515.23 ± 26.84a

204.07 ± 0.90e

161.59 ± 0.49f

146.26 ± 0.55 g

104.35 ± 0.09 h

303.26 ± 0.19d

391.31 ± 1.17b

373.14 ± 0.52c

14

33.676

   

Unknown acetyl-anthocyanin

 

ND

ND

ND

ND

8.87 ± 0.70c

19.72 ± 0.55a

13.03 ± 0.47b

15

34.289

   

Unknown acetyl-anthocyanin

 

ND

ND

ND

ND

ND

2.29 ± 0.07a

2.40 ± 0.30a

16

38.056

   

Malvidin-3-O-(6″-acetyl)galactoside

 

8.42 ± 0.79d

7.73 ± 0.75e

5.79 ± 0.69f

3.25 ± 0.55 g

25.02 ±  1.64b

33.09 ± 2.17a

18.77 ± 1.67c

  1. ND not detected
  2. A: Data are mean ± S.D. Values in the same row with different superscript letters are significantly different (P < 0.05) using ANOVA with Duncan’s multiple comparison test, n = 3
  3. B: Individual anthocyanin content is expressed as micrograms of Cyanidin-3-O-glucoside per gram of sample
  4. C: HAD Hot air drying (40, 50, 60, and 70 °C), FD Freeze drying, MVD Microwave vacuum drying, and MFD Microwave freeze vacuum drying